Down To Old Maui Lyrics — Vibrations Of Molecules: Near Infrared Spectroscopy In Action

Chorus (after each verse): Rolling down to old Maui, me boys. Writer(s): James Roger Mcguinn Lyrics powered by. Sailing, Wailing and Failing with Captain Falcore! Use the citation below to add these lyrics to your bibliography: Style: MLA Chicago APA. Off to Sea Once More. With a big, fat, aching head. "Rolling Down to Old Maui" is a traditional sea shanty about whalers in the North Pacific Ocean longing for home in Maui, Hawaii.

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Rollin Down To Old Maui

Rolling Down To Old Maui Song History

1850 Kamchatka bowhead whale and Pacific sperm whale fishing. And the coconut fronds. And them coconut fronds in them tropic lands. A gutsy anticipation of the joys of the Southern Isles after the hardship on Northern Seas. Rolling down to old Maui is a whaling sea song that finds its origins back to the XVIII century. The noble tune is from Chantying Aboard American Ships by F. P. Harlow. Included in 1999 on the same-named Fellside anthology CD. Now the ice is far astern. CHORUS: Rolling down to old Maui(1), me boys, rolling down to old Maui, We're homeward bound. Dreadnoughts, The - Daughters Of The Sun.

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Wind and rain, Them coconut fronds, them tropical shores, we soon shall see again; Six hellish months we′ve passed away on the cold Kamchatka sea, But now we′re bound from the Arctic grounds, rolling down to old Maui. The district was known all over the world for its riotous debauches, and the whalemen accordingly felt called upon to go on their wildest sprees in Honolulu. " Maui is one of the Hawaiian Islands and was a meeting place for whalers… something to look forward to between trips. The third verse came from a wandering Drambuie drinker, Dave Alexander, who doubles as a good singer. And them native maids. Our stans'l booms is carried away, what care we for that sound, A living gale is after us, thank God we're homeward bound. We're homeward bound from the arctic ground, Through the ice and sleet and rain: And the coconut fronds in the tropic lands, We soon shall see again! One historian wrote, "Cape Horn, " the whorehouse district [of Honolulu], was so named because of the truism that the whalemen hung their consciences on the Horn on the voyage out and picked them up again on the way home. They greet us now we're found: And now ashore, we'll have good fun, We'll paint those beaches red; Awaking in the arms of a wahine, With a big fat aching head! In March they fitted out for the summer season in the Arctic, when they fished the bowhead grounds off Kamchatka and the Gulf on Anadyr. Rolling Down to Old Mohee from the journal of the Atkins Adams, 1858.

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They noted: We learned this whaling song from Ian Robb, a fine singer, originally from St Albans, now living in Ottawa, with whom John used to sing while studying in Canada. Full Friendship followed by Battle Royale! Once more we sail with the northerly gale, towards our island home. Six brutal months have passed away.

Down To Old Maui Lyrics

Oh, the deck's a raging sea. An ample share of toil and care we whalemen undergo, But when it's over, what care we how the bitter the blast may blow? Het gebruik van de muziekwerken van deze site anders dan beluisteren ten eigen genoegen en/of reproduceren voor eigen oefening, studie of gebruik, is uitdrukkelijk verboden. Bill Price sang Old Maui in 1978 on his Autogram album I Sing As I Please. Collected by Stan Hugill. The deck is hid from view. Stream me up Scotty! We're homeward bound! Live photos are published when licensed by photographers whose copyright is quoted. The words are clearly related to the Huntington version. Is a-waiting our return. Oh, it's many a day we toiled away in that cold Kamchatka Sea.

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Conversely the most intense bands at 758 and 717 overlap to give one large peak. Software for fitting: Software for spectra and vibration analysis: Companies: Tutorials and other links: - Horiba Raman tutorial. KBr is permeable to 400 cm-1. The mass spectrum of a hydrocarbon is shown below.

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CaF2 / Fe2O3||12000 - 1200 cm-1|. Red is red, active pity. Spectra acquisition conditions depend on sample particle size, packing density and homogeneity. Molecules that possess permanent dipole moment are IR inactive. Complex polyatomic molecules like carbon dioxide have more possible vibrations. The IR spectrum of the unknown molecule with molecular formula C5H₁0O is given below. Allowed transitions become smaller in energy. A disadvantage is their low operation temperature of 15 - 90 K. Other examples, such as the gallium arsenide -, or gallium aluminium arsenide lasers work in the IR region, and can be operated at room temperature. History of IR spectroscopy. Twisting (out-of-plane). Select the vibrations that should be infrared active. energy. The different vibrations of the different functional groups in the molecule give rise to bands of differing intensity. Journal of Chemical Education, 68, no. This changing dipole results in a molecular oscillating electric field.

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3) atomic nuclei (e. g., alpha particles). Q: The molecule with strong absorptions at 1800 and 1760 cm ^ -1 is: A: IR is an important spectroscopic technique to characterize the organic compounds. In geosciences it is a sensitive tool for mineral identification, since every mineral has a characteristic spectrum. However, the levels of vibration are quantized and are given by 'v'. KBr/Ge||6500 - 450 cm-1|. Input from accelerated predictive stability (APS) studies to pharmaceutical development. So, if a molecule has dipole moment it is…. This creates a vibrating electrical dipole – a sort of "antenna" – which is why this vibration is infrared active. 5 µm can be reached. Multiplying the frequency in wavenumbers by the speed of light ( 3x10^10 cm/sec) will give the frequency sec-1. Only the A1, B1, and B2 are infrared active while the A2 vibration is infrared inactive. Most of the crystals don't have an ideal crystal lattice, they are not perfect, but contain a certain number of lattice defects, which can be caused by e. g., temperature, pressure, crystal growth, radiation or phase transitions. P. Select the vibrations that should be infrared active.com. Bernard-Moulin, M. Boiret, R. Frances, M. Meunier (†), E. Ziemons. Hydrogen Bonding in water molecules.

Select The Vibrations That Should Be Infrared Active Sites

Use the Rule of 13 to determine a molecular…. The challenge is to design sensors that are able to acquire spectra very rapidly from samples moving on a conveyor belt. Select the vibrations that should be infrared active sites. In spectroscopic work it is common to use the wave number per centimeter instead of the wavelength. A corresponding measure is the absorption coefficient, which is the negative decimal logarithm of this intensity ratio for 1 cm of sample. The normal modes of vibration of linear and bent triatomic molecules are illustrated and some common linear and bent triatomic molecules are shown below.

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Ingénieur Polytech Orléans, PhD en spectrométrie de masse et traitement du signal, Y. Further applications are: - mineral identification and structural characterization. A: In IR spectrum C-N streching in aromatic amine show a strong peak in the range of 1340-1260 cm-1. ATR is insensitive to sample thickness, the effective penetration depth is a fraction of a wavelength. Absorption of light with the appropriate energy ( h = E1-E0) allows the molecule to become "excited" into the next higher vibrational energy state E1. Daily Quiz 2 Organic CHemistry Flashcards. Related Chemistry Q&A. Scissoring (in-plane).

In niR spectroscopy the signals observed are non-specific. Some advantages and disadvantages of infrared spectroscopy are listed in table 2. The energy levels of vibration are given by: - The selection rule for the IR spectra is that the change or jump in vibrational levels should be Δ v = 1. Calculate wavenumber for C=C and C=C by Hook's law. Infrared and Raman spectroscopy. Doesn'T change polarity coming to the fifth option it is in florid active in active by because the c c l bond is polar. For other materials it can be calculated with following equation: cn = c0 / n, where cn is speed of light in medium, n is the refractive index of the medium. Symmetric compounds have no dipole ymmetriccompounds have dipole moment.